There's two details that are important to highlight. tokio is actually 2 components, it's the async scheduler, and it's the IO runtime. Pollster is only a scheduler, and does not offer any IO functionality. You can actually use tokio libraries with pollster, but you need to register the IO runtime (and spawn a thread to manage it) - this is done with Runtime::enter() and it configures the thread local interface so any uses of tokio IO know what runtime to use.

There are ideas to abstract the IO runtime interface into the async machinery (in Rust that's the Context object that schedulers pass into the Future) but so far that hasn't gotten anywhere.